There is known problem with macOS Sierra 10.12.2+ and slideshows created in PicturesToExe 6.0 - 8.0.21. Slideshows do not start and only black screen appears.
Solution 1:
Download and install PicturesToExe 8.0.23.
Or download new PicturesToExe 9.
Open project file with existing slideshow and create a new presentation folder for Mac.
Solution 2
You can repair existing slideshows for Mac using special free utility:
https://files.wnsoft.com/soft/RepairMacPresenta